Laboratory solid waste from practical activity as activated carbon precursor for reducing methylene blue in the laboratory wastewater Pemanfaatan Limbah Tanaman Kegiatan Praktikum Sebagai Bahan Dasar Karbon Aktif untuk Menurunkan Kadar Metilen Biru pada Limbah Cair Laboratorium

Main Article Content

Aninda Tifani Puari

Abstract

Activated carbon (AC) from agricultural waste has become one promising way to produce AC regarding to low price of the precursor and its effect to environment. In this research, the solid waste from the basic biology practical in UPT. Basic and Central Laboratory, Andalas University (Unand) was utilized as the precursor for producing low price AC. The activation was done by chemical activation using three different activating agents which were zink chloride (ZnCl2), phosphoric acid (H3PO4), potassium hydroxide (KOH). The carbonization process was done at temperature of 700°C. The precursor and three different AC after activation were characterized using fourier-transform infrared spectroscopy (FT-IR) to examine  the functional group and scanning electron microscope (SEM) to observe the pores structure. The adsorption efficiency (AE) of each AC on methylene blue (MB) contained in laboratory wastewater was examined through adsorption process with retention time of 30 minutes at room temperature and neutral pH. SEM analysis showed that the three activating agents were resulting in higher surface area and more pores were formed. The highest AE of MB from laboratory wastewater for each AC were 97,5 %, 96,31%, and 90,79 for KOH, , ZnCl2, and H3PO4, respectively. Meanwhile, the highest adsorption capacity was achieved by AC through KOH activation with 0,003 mg/g

Downloads

Download data is not yet available.

Article Details

How to Cite
Puari, A. (2021). Laboratory solid waste from practical activity as activated carbon precursor for reducing methylene blue in the laboratory wastewater. Jurnal Temapela, 3(2), 73-79. https://doi.org/10.25077/temapela.3.2.73-79.2020
Section
Articles

References

Amelia, S., & Maryudi, M. (2019). Application of Natural Zeolite in Methylene Blue Wastewater Treatment Process by Adsorption Method. Jurnal Bahan Alam Terbarukan, 8(2), 144–147. https://doi.org/10.15294/jbat.v8i2.22480
Anisuzzaman, S. M., Joseph, C. G., Daud, W. M. A. B. W., Krishnaiah, D., & Yee, H. S. (2015). Preparation and characterization of activated carbon from Typha orientalis leaves. International Journal of Industrial Chemistry, 6(1), 9–21. https://doi.org/10.1007/s40090-014-0027-3
Berhe, S., Ayele, D., Tadesse, A., & Mulu, A. (2015). Adsorption Efficiency of Coffee Husk for Removal of Lead ( II ) from Industrial Effluents : Equilibrium and kinetic study. International Journal of Scientific and Research Publications, 5(9), 1–8.
Bhatnagar, A., Hogland, W., Marques, M., & Sillanpää, M. (2013). An overview of the modification methods of activated carbon for its water treatment applications. Chemical Engineering Journal, 219, 499–511. https://doi.org/10.1016/j.cej.2012.12.038
Blinová, L., Sirotiak, M., Bartošová, A., & Soldán, M. (2017). Review: Utilization of Waste From Coffee Production. Research Papers Faculty of Materials Science and Technology Slovak University of Technology, 25(40), 91–101. https://doi.org/10.1515/rput-2017-0011
Coates, J. (2000). Interpretation of Infrared Spectra, A Practical Approach Interpretation of Infrared Spectra, A Practical Approach. In Encyclopedia of Analytical Chemistry. In Soil Science (Vol. 112, Issue 1, pp. 10815–10837). John Wiley & Sons Ltd. https://doi.org/10.1097/00010694-197107000-00005
D. Rodriguez-Lopez, A., Garcia-Garrido, J., Perez-Ramiro, C., & M. Garcia-Castello, E. (2013). Discoloration on Methylene Blue Solutions by Direct and Catalytic Ozonation. Journal of Materials Science and Chemical Engineering, 01(05), 33–38. https://doi.org/10.4236/msce.2013.15007
Etim, U. J., Umoren, S. A., & Eduok, U. M. (2016). Coconut coir dust as a low cost adsorbent for the removal of cationic dye from aqueous solution. Journal of Saudi Chemical Society, 20, S67–S76. https://doi.org/10.1016/j.jscs.2012.09.014
Ferrero, F. (2007). Dye removal by low cost adsorbents: Hazelnut shells in comparison with wood sawdust. Journal of Hazardous Materials, 142(1–2), 144–152. https://doi.org/10.1016/j.jhazmat.2006.07.072
González-García, P. (2018). Activated carbon from lignocellulosics precursors: A review of the synthesis methods, characterization techniques and applications. Renewable and Sustainable Energy Reviews, 82, 1393–1414. https://doi.org/10.1016/j.rser.2017.04.117
Hameed, B. H., Din, A. T. M., & Ahmad, A. L. (2007). Adsorption of methylene blue onto bamboo-based activated carbon: Kinetics and equilibrium studies. Journal of Hazardous Materials, 141(3), 819–825. https://doi.org/10.1016/j.jhazmat.2006.07.049
Khodaie, M., Ghasemi, N., Moradi, B., & Rahimi, M. (2013). Removal of methylene blue from wastewater by adsorption onto znclactivated corn husk carbon equilibrium studies. Journal of Chemistry, 2013. https://doi.org/10.1155/2013/383985
Mahmoud, M. S., Farah, J. Y., & Farrag, T. E. (2013). Enhanced removal of Methylene Blue by electrocoagulation using iron electrodes. Egyptian Journal of Petroleum, 22(1), 211–216. https://doi.org/10.1016/j.ejpe.2012.09.013
Moreno-Castilla, C., Carrasco-Marín, F., López-Ramón, M. V., & Alvarez-Merino, M. A. (2001). Chemical and physical activation of olive-mill waste water to produce activated carbons. Carbon, 39(9), 1415–1420. https://doi.org/10.1016/S0008-6223(00)00268-2
Ooi, C. H., Cheah, W. K., Sim, Y. L., Pung, S. Y., & Yeoh, F. Y. (2017). Conversion and characterization of activated carbon fiber derived from palm empty fruit bunch waste and its kinetic study on urea adsorption. Journal of Environmental Management, 197, 199–205. https://doi.org/10.1016/j.jenvman.2017.03.083
Örkün, Y., Karatepe, N., & Yavuz, R. (2012). Influence of temperature and impregnation ratio of H3PO 4 on the production of activated carbon from hazelnut shell. Acta Physica Polonica A, 121(1), 277–280. https://doi.org/10.12693/APhysPolA.121.277
Pathak, P. D., Mandavgane, S. A., & Kulkarni, B. D. (2015). Fruit peel waste as a novel low-cost bio adsorbent Bitter gourd peel Banana peel Cassava peel Citrus peel Carrot peel Grapefruit peel Garlic peel Green Pea peels Guava peel Kohlrabi peel Mango peel Onion peel Pineapple peel Pomegranate peel Potato peel 1. 1, 3–6.
SNI. (2009). Standar Nasional Indonesia Air dan air limbah-Bagian 8: Cara uji timbal (Pb) dengan Spektrofotometri Serapan Atom (SSA)-nyala Badan Standardisasi Nasional.
Yakout, S. M., & Sharaf El-Deen, G. (2016). Characterization of activated carbon prepared by phosphoric acid activation of olive stones. Arabian Journal of Chemistry, 9, S1155–S1162. https://doi.org/10.1016/j.arabjc.2011.12.002
Zhou, J., Luo, A., & Zhao, Y. (2018). Preparation and characterisation of activated carbon from waste tea by physical activation using steam. Journal of the Air and Waste Management Association, 68(12), 1269–1277. https://doi.org/10.1080/10962247.2018.1460282